The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Sep. 16, 1997
Filed:
Feb. 16, 1995
Alain Forestiere, Vernaison, FR;
Pierre Yout, Vienne, FR;
Henri Delhomme, Sainte Foy les Lyrons, FR;
Institut Francais du Petrole, Rueil Malmaison, FR;
Abstract
The invention concerns a process and catalyst for the production of cyclohexane by hydrogenation of benzene, comprising at least the two following steps: a) gradually introducing the feed of benzene for hydrogenation and a hydrogen-rich gas into a reaction zone containing a cyclohexane-rich liquid and a nickel-based catalyst in colloidal suspension and recovering a gaseous phase containing cyclohexane, hydrogen and benzene; b) introducing the gaseous phase into a reactor operating under hydrogenation conditions and containing at least one fixed bed of a solid nickel-based hydrogenation catalyst, wherein the nickel-based catalyst used in step a) is a product which results from the reduction, by at least one trialkylaluminium compound, of a solution of at least one nickel carboxylate and at least one sodium carboxylate in solution, the Ni:Na molar ratio being between 2:1 and 1000:1 in a hydrocarbon or a hydrocarbon mixture.