The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 03, 1996

Filed:

Sep. 15, 1995
Applicant:
Inventors:

Friedrich Baucke, Mainz, DE;

Thomas Pfeiffer, Ingelheim, DE;

Sylvia Biedenbender, Bingen, DE;

Gernot Roth, Dalheim, DE;

Ralf-Dieter Werner, Laufersweiler, DE;

Assignee:

Schott Glaswerke, Mainz, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G01N / ;
U.S. Cl.
CPC ...
205782 ; 2057855 ; 205786 ; 204435 ; 204422 ; 204423 ; 204412 ; 422 681 ; 422 8212 ;
Abstract

The method of electrochemical determination of oxygen partial pressure in ionic melts includes providing a metal/metal oxide reference electrode consisting of an electrode body made of a metal selected from the group consisting of Mo, W, Hf, Nb and Ta and alloys thereof and a layer of an oxide of that metal on the electrode body; immersing a pure platinum electrode and the metal/metal oxide reference electrode in a glass melt; measuring a potential across the metal/metal oxide reference electrode and the pure platinum electrode immersed in the glass melt to obtain a measured potential characteristic of the oxygen partial pressure in the glass melt; obtaining a calibration curve relating the potential across said reference electrode and the pure platinum electrode to the oxygen partial pressure in the glass melt as a function of temperature; and obtaining the oxygen partial pressure in the glass melt from the measured potential and the calibration curve. Either the calibration curve is obtained experimentally by immersing a Zirconium dioxide electrode in the glass melt and measuring a potential difference between the metal/metal oxide reference electrode and the Zirconium dioxide electrode at a plurality of temperatures or theoretically from thermodynamic data for the metal/metal oxide reference electrode.


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