The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 25, 1996

Filed:

Dec. 30, 1994
Applicant:
Inventors:

Bruce G Aitken, Erwin, NY (US);

George H Beall, Big Flats, NY (US);

James E Dickinson, Jr, Corning, NY (US);

Assignee:

Corning Incorporated, Corning, NY (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C03C / ; C03C / ; C03C / ; C03C / ;
U.S. Cl.
CPC ...
501 45 ; 501 46 ; 501 47 ; 501 48 ; 65 321 ; 651341 ;
Abstract

The subject invention is directed at glasses wherein either a portion of the ZnO or alkali metals, or both, is replaced by Cu.sub.2 O, i.e., monovalent copper. Specifically, the present invention is directed at a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, 28-42% P.sub.2 O.sub.5, 15-30% Cu.sub.2 O, 10-30% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O, and up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-2% Ln.sub.2 O.sub.3, 0-10 Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3, 0-10 Fe.sub.2 O.sub.3 0-10% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Fe.sub.2 O.sub.3, 0-7% MoO.sub.3 0-7% WO.sub.3 0-7% MoO.sub.3 +WO.sub.3, and 0-8% F, the latter as analyzed in weight percent. In addition, it is necessary that the predominate proportion of the copper in the glass is present in the cuprous or Cu.sup.+ oxidation state. These inventive glasses exhibit a transition temperature normally below about 300.degree. C., a working temperature below about 400.degree. C., while, at the same time, exhibiting excellent resistance to attack by water.


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