The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 11, 1996

Filed:

Sep. 22, 1994
Applicant:
Inventors:

Robert I Mink, Warren, NJ (US);

Thomas E Nowlin, West Windsor, NJ (US);

Pradeep P Shirodkar, Somerset, NJ (US);

Sandra D Schregenberger, Neshanic, NJ (US);

Grace O Tsien, Colonia, NJ (US);

Assignee:

Mobil Oil Corporation, Fairfax, VA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ;
U.S. Cl.
CPC ...
525246 ; 525247 ; 525268 ; 525270 ; 525324 ; 526 78 ; 526 80 ; 526 81 ; 526 86 ; 526 92 ; 526114 ; 526129 ;
Abstract

A bimetallic catalyst produces broad or bimodal molecular weight distribution polyolefin resin whose composition depends on the ratio of the concentration of the two metals of the catalyst producing the HMW and LMW components. The bimetallic catalyst produces a broad/bimodal MWD resin whose HMW and LMW components depend on the relative productivity of each of the transition metal sites of the catalyst. Water and/or carbon dioxide are cofed to the polymerization reactor at levels necessary to modify the weight fractions of the HMW and LMW components, thus achieving a target molecular weight distribution, MWD. The invention allows the resin MWD to be adjusted in the reactor. The weight fraction of the high molecular weight component decreases with the addition of the water and or the carbon dioxide and the FI of the overall product increases with a decrease in the HMW component weight fraction in the product.


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