The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 04, 1996

Filed:

Aug. 19, 1994
Applicant:
Inventors:

Magdalena Ramirez de Agudelo, Edo. Miranda, VE;

Trino J Romero, Caracas, VE;

Emilia Mujica, San Antonio de Los Altos, VE;

Assignee:

Intevep, S.A., Caracas, VE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J / ; B01J / ;
U.S. Cl.
CPC ...
502159 ; 502324 ; 502325 ; 502326 ; 502329 ; 502330 ; 502331 ; 502333 ; 502335 ; 502336 ; 502337 ; 502338 ; 502339 ; 502340 ; 502343 ;
Abstract

A catalyst for production of alkyl tert alkyl ether from sulfur contaminated feedstock includes an ion exchange resin; a palladium first metal phase supported on the resin; and a sulfur inhibiting second metal phase supported on the resin for inhibiting sulfur deactivation of the first metal phase, wherein the first metal phase is present at an atomic ratio to the second metal phase of between about 1:20 to about 1:0.1. A process for producing alkyl tert alkyl ethers includes the steps of providing a liquid olefinic hydrocarbon feedstock containing sulfur and having a total sulfur content of up to about 300 ppm; providing a catalyst as described above; mixing the feedstock with alcohol and hydrogen to obtain a reaction feedstock; and contacting the reaction feedstock with the catalyst under etherification conditions so as to produce alkyl tert alkyl ether.


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