The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Mar. 21, 1995
Filed:
Oct. 12, 1993
Guenther Doellein, Hanover, DE;
Solvay Deutschland GmbH, Hanover, DE;
Abstract
A method for producing Ph.sub.3 C[B(C.sub.6 F.sub.5).sub.4 ] in an improved yield by reacting LiB(C.sub.6 F.sub.5).sub.4, which has not been isolated between production and use, with Ph.sub.3 CCl preferably in a molar ratio of LiB(C.sub.6 F.sub.5).sub.4 to Ph.sub.3 CCl of 1:(1.+-.0.05), and preferably in the presence of a hydrocarbon solvent such as an aliphatic hydrocarbon containing from 5 to 8 carbon atoms, to give a Ph.sub.3 C[B(C.sub.6 F.sub.5).sub.4 ] product; optionally evaporating the hydrocarbon solvent; extracting the resulting Ph.sub.3 C[B(C.sub.6 F.sub.5).sub.4 ] product; separating insoluble LiCl, and isolating the product. The product may be isolated, for example, by freeing it of solvent, thereafter dissolving the product in toluene to form a toluene solution, introducing the toluene solution into a hydrocarbon solvent to form crystals of the product, and recovering the crystals. In the method, the LiB(C.sub.6 F.sub.5).sub.4 is used in the form of a hydrocarbon preparation, preferably a reaction mixture obtained in the synthesis of LiB(C.sub.6 F.sub.5).sub. 4, the concentration of may be adjusted by concentrating or diluting as needed to obtain a preferred LiB(C.sub.6 F.sub.5).sub.4 concentration of from 20 to 300 grams/liter.