The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 07, 1995

Filed:

Jul. 12, 1993
Applicant:
Inventors:

Marlin E Walters, West Columbia, TX (US);

W Frank Richey, Lake Jackson, TX (US);

Katherine S Clement, Lake Jackson, TX (US);

Steven L Brewster, Lake Jackson, TX (US);

Emmett L Tasset, Lake Jackson, TX (US);

Paul M Puckett, Lake Jackson, TX (US);

V Rao Durvasula, Lake Jackson, TX (US);

Hong A Nguyen, Lake Jackson, TX (US);

Assignee:

The Dow Chemical Company, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C / ; C07C / ; C07B / ;
U.S. Cl.
CPC ...
568779 ; 562480 ; 564305 ; 564312 ; 564314 ; 564405 ; 564430 ; 564433 ; 568721 ; 568722 ; 568727 ; 568774 ; 570123 ; 570143 ; 570206 ;
Abstract

Compounds having acidic protons and a molecular structure which can delocalize the electron density of the conjugate base (target compounds) are chlorinated by contacting such compounds with a perchloroalkane and aqueous base in the presence of a phase transfer catalyst which is an tetraalkylammonium hydroxide. Chlorinated products, preferably gem-dichloro compounds, are produced. The gem-dichloro compounds are useful for alkylation of aromatic compounds. For instance fluorene is chlorinated to form 9,9-dichlorofluorene which is reacted with such compounds as phenol or aniline to form such compounds as 9,9-bis(hydroxyphenyl)fluorene, 9,9-bis(aminophenyl)fluorene, or 9-aminophenyl-9-chlorofluorene.


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