The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 15, 1994

Filed:

Jun. 24, 1992
Applicant:
Inventors:

Martin Wallau, Mainz, DE;

Rudolf Spichtinger, Frankfurt, DE;

Klaus K Unger, Bensheim, DE;

Arno Tissler, Bonn, DE;

Roland Thome, Bonn, DE;

Assignees:

VAW Aluminium AG, Bonn, DE;

Veba OEL AG, Gelsenkirchen-Hassel, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C / ; C01B / ; B01J / ;
U.S. Cl.
CPC ...
585418 ; 585407 ; 585417 ; 423326 ; 423333 ; 502 61 ; 502 70 ;
Abstract

The invention relates to a crystalline zeolite-like gallosilicate having an atomic ratio of Si/Ga in the outer crystalline surface that is not larger than the average Si/Ga ratio for the whole of the crystal. The invention also relates to a method of making such a gallosilicate comprising the hydrothermal crystallization of a strictly inorganic reaction mixture having the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05-1.0; and H.sub.2 O/SiO.sub.2 =10-1,000. The invention further relates to the above-described method wherein said reaction mixture is prepared by adding an aged gel to a first mixture, the first mixture preferably having a composition with the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05 to 1.0; and H.sub.2 O/SiO.sub.2 =20 to 100.


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