The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Nov. 30, 1993
Filed:
Jun. 02, 1992
Nissan Motor Company, Ltd., Yokohama, JP;
Abstract
The disclosure relates to a metal oxide film formed on a glass substrate by a sol-gel method using a solution of at least one metal alkoxide or acetylacetonate. Water which is in the amount ranging from 50 to 400 mol % of the at least one metal alkoxide or acetylacetonate, an organic solvent and a catalyst are added to the solution, thereby to form a first sol. To afford water repellency to the oxide film, a fluoroalkylsilane in the amount more than 0.30 mol % of and less than 3.0 mol % of the at least one metal alkoxide or acetylacetonate, or an alkylsilane compound in the amount more than 4.0 mol % of and less than 20 mol % of the at least one metal alkoxide or acetylacetonate, is added to the first sol, thereby forming a second sol. The concentration of the at least one metal alkoxide or acetylacetonate in the second sol is adjusted to fall within the range from 0.005 to 3.0 mol %. The second sol is applied to the glass substrate to form a gel film. The gel film is heated at a temperature not lower than 100.degree. C. The obtained oxide film is superior in durability of water repellency.