The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Aug. 10, 1993
Filed:
Apr. 08, 1991
Mohammed Dekiouk, Woustviller, FR;
Gerard Hecquet, Bethune, FR;
Stanislas Pietrzyk, Mons en Baroeul, FR;
Atochem, Paris, FR;
Abstract
For the oxidative dehydrogenation of saturated carboxylic acids to form .alpha.,.beta.-unsaturated carboxylic acids, saturated acids are contacted with a gas containing molecular oxygen and, where appropriate, an inert diluent gas, in the vapor phase, at a reaction temperature of 250.degree. to 600.degree. C., in the presence of a catalyst system comprising a non-supported catalyst of the formula FeP.sub.x Me.sub.y O.sub.z, wherein: Me is at least one of the following elements: Li, Na, K,, Rb, Cs, Mg, Ca, Sr and Ba; x has a value from 0.2 to 3.0; y has a value from 0.01 to 0.2; and z is the quantity of oxygen bonded to the other elements and corresponding to their oxidation state, in an entrained-bed reactor and, where appropriate, in the presence of steam in a molar ratio to the saturated acid not exceeding 0.5. The catalyst is beneficially associated with at least one zeolite, preferably in a concentration sufficient to improve the attrition resistance of the catalyst, e.g., in an amount by weight of about 1-10% of the catalyst.