The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Jun. 08, 1993
Filed:
Sep. 27, 1991
Applicant:
Inventor:
Michael D Jones, Hanworth, GB;
Assignee:
The British Petroleum Company p.l.c., London, GB;
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C / ; C07C / ;
U.S. Cl.
CPC ...
562517 ; 562519 ; 554129 ; 554132 ; 554154 ;
Abstract
An improved liquid-phase process for preparing carboxylic acids having (n+1) carbon atoms by rhodium catalyzed carbonylation of an alcohol having n carbon atoms is provided. The process is particularily suitable for preparing acetic acid from methanol in commercial carbonylation reactors operating at steady-state with a low standing quantity of water (e.g. 0.5 to 5% by weight). The improvement lies in carrying out the carbonylation in the presence of an iodide stabilizer (e.g. lithium iodide) and a Group VI B metal costabiliser. The process can optionally be carried out in the presence of hydrogen.