The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Feb. 02, 1993
Filed:
Oct. 25, 1991
William G Etzkorn, Cross Lanes, WV (US);
Gordon G Harkreader, Charleston, WV (US);
Union Carbide Chemicals & Plastics Technology Corporation, Danbury, CT (US);
Abstract
The process for oxidation of propylene to acrolein and the oxidation of propylene to acrylic acid in two stages with acrolein as an intermediate are improved by use of essentially inert essentially anhydrous diluent gases to replace steam in the reaction streams. In particular, the use of essentially inert essentially anhydrous diluents which raise the composite heat capacity of the diluent gas mixture to at least about 6.5 calories/(gram-mole) (.degree.C.) will improve selectively to desired products and will reduce both the waste water load on the system and by-product formation. Reduction in second-stage catalyst efficiency is compensated for by introducing steam to the feed to the second-stage, and/or by increasing the operating temperature of the second-stage, and/or by increasing the active surface area of the second-stage catalyst.