The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 08, 1992

Filed:

Oct. 19, 1990
Applicant:
Inventors:

Tetsuya Tsunekawa, Otsu, JP;

Tetsuya Gotoh, Otsu, JP;

Keiichi Egawa, Otsu, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C / ;
U.S. Cl.
CPC ...
564273 ; 548570 ; 549404 ; 558414 ; 558422 ; 560 35 ; 562440 ; 564152 ; 564153 ; 564157 ; 564163 ; 564185 ; 564212 ; 564213 ; 564272 ; 564274 ;
Abstract

The present invention provides an organic nonlinear optical material including a benzylidene-aniline derivative having an electron-donating substituent introduced at the 4-position and an electron-accepting substituent introduced at the 4'-position, by selecting as the conjugated .pi. electronic system a benzylidene-aniline derivative having a large molelcular hyperpolarizability and yet a dipole moment as small as those of benzene derivatives, and introducing a molecular alignment-regulating substituent. The centrosymmetry in the bulk state of the material, for example, in the crystal state, is destroyed and the molecular alignment is regulated to such a bulk structure so that the optical nonlinearity possessed by the molecule is effectively utilized. The material exhibit a large optical nonlinearity never attained by conventional techniques. the intermolecular cohesive force due to the .pi. electron interaction between the molecules in the present invention is larger than that between a benzene derivative. Consequently, the material has, comparatively, a high melting point, a low subliming property, and a low water-absorbing property. In conclusion, a practically invaluable nonlinear optical material having a high durability in the bulk state and an excellent resistance to laser damage is provided.


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