The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 24, 1991

Filed:

Jan. 23, 1989
Applicant:
Inventors:

Alan E Platt, Midland, MI (US);

Jerry L Hahnfeld, Midland, MI (US);

David A Habermann, Midland, MI (US);

Assignee:

The Dow Chemical Company, Midland, MI (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08F / ; C08F / ; C08F / ; C08F / ;
U.S. Cl.
CPC ...
522 63 ; 522 78 ; 522 79 ; 522116 ; 522120 ; 522129 ; 525244 ; 525315 ; 525388 ;
Abstract

An improved process for forming hydroperoxide derivatives of rubbery polymers. The hydroperoxide derivatives being particularly well suited for use as intermediates in forming graft rubbery polymers. The process involves dissolving a rubbery polymer in a monomer mixture and adding to the rubbery polymer/monomer mixture a photosensitizing agent. The rubbery polymer-monomer mixture is then oxygenated and exposed to light under conditions wherein triplet oxygen is converted to singlet oxygen. The improvement comprises adding to the rubbery polymer/monomer mixture a solvent capable of solubilizing the photosensitizing agent in the rubbery polymer/monomer mixutre. The solubilizer increases the yield of hydroperoxide derivatives of rubbery polymers formed by a factor of 3.


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