The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
May. 14, 1991
Filed:
Mar. 06, 1989
Fuji Photo Film Co., Ltd., Kanagawa, JP;
Abstract
A method of forming a direct positive image comprising: (a) imagewise exposing a direct positive silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer containing non-prefogged internal latent image silver halide grains, at least one hydrophilic colloidal layer of the material containing a nucleating agent, and at least one sensitizing dye represented by formulae (I), (Ia), (Ia'), or (Ib): ##STR1## wherein Z and Z.sub.1 each represents a non-metallic atomic group necessary for forming a 5-membered or 6-membered nitrogen-containing heterocyclic ring; R and R.sub.1 each represents a substituted or unsubstituted alkyl group or an aryl group; Q and Q.sub.1 represent a non-metallic atomic group necessary for forming together a 4-thiazolidinone group, a 5-thiazolidinone group or a 4-imidazolidinone group; L, L.sub.1 and L.sub.2 each represents a methine group or a substituted methine group; n.sub.1 and n.sub.2 each is 0 or 1; X represents an anion; and m is 0 or 1; ##STR2## wherein R.sub.21 and R.sub.22 each represents a substituted or unsubstituted alkyl group; R.sub.20 represents hydrogen, a methyl group, a methoxy group or an ethoxy group; R.sub.23 and R.sub.24 each represents hydrogen, a lower alkyl group, a phenyl group or a benzyl group; R.sub.25 represents hydrogen, a lower alkyl group, a lower alkoxy group, a phenyl group, a benzyl group or ##STR3## wherein W.sub.1 and W.sub.2 each represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and W.sub.1 and W.sub.2 may be linked to form a 5-membered or 6-membered nitrogen-containing heterocyclic ring; D.sub.20 represents a substituted or unsubstituted group containing at least one ethylene bond; D.sub.21 and D.sub.22 each represents hydrogen or a group containing an ethylene bond, when D.sub.21 and D.sub.22 are linked to form a ring; Z.sub.20 and Z.sub.21 each represents a non-metallic atomic group necessary for forming a 5- membered or 6-membered nitrogen-containing heterocyclic ring; X' represents an acid anion; and n' is 1 or 2; ##STR4## wherein R.sub.36 and R.sub.37 each has the same definition as R.sub.21 ; R.sub.38 has the same definition as R.sub.23 ; V represents hydrogen, a lower alkyl group, an alkoxy group, a halogen atom, or a substituted alkyl group; Z.sub.32 has the same definition as R.sub.20 ; X.sub.1 has the same definition as X; and m.sub.1, n.sub.1 and p is each 1 or 2 and (b) developing said exposed material in the presence of a nucleation accelerator to form a positive image.