The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 03, 1990

Filed:

Sep. 28, 1989
Applicant:
Inventors:

Richard K Helling, Martinez, CA (US);

Philip D Grover, Concord, CA (US);

Thomas J Dietsche, Berkeley, CA (US);

Mark L Garibaldi, Martinez, CA (US);

Assignee:

The Dow Chemical Company, Midland, MI (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D / ;
U.S. Cl.
CPC ...
546345 ;
Abstract

The relative amounts of 5,6-dichloro-2-(trichloromethyl)pyridine and 3,6-dichloro-2-(trichloromethyl)pyridine obtained in the chlorination of 2-chloro-6-(trichloromethyl)pyridine in the liquid phase at temperatures of about 160.degree. C. to about 220.degree. C. and in the presence of a metal halide catalyst, such as ferric chloride, are controlled by regulating the amount of hydrogen chloride present in the system, adding hydrogen chloride to obtain a mixture enriched in 5,6-dichloro-2-(trichloromethyl)pyridine or removing hydrogen chloride, usually by passing excess chlorine or an inert gas through the system, to obtain a mixture enriched in 3,6-dichloro-2-(trichloromethyl)pyridine.


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