The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 19, 1990

Filed:

Oct. 09, 1987
Applicant:
Inventors:

Gerard Picard, Fontenay sous Bois, FR;

Yves Bertaud, St. Jean de Maurienne, FR;

Evelyne Prat, Paris, FR;

Michel Leroy, St. Egreve, FR;

Assignee:

Aluminium Pechiney, Paris, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G01N / ;
U.S. Cl.
CPC ...
20415316 ; 204422 ;
Abstract

The invention concerns a process and apparatus for electrochemical measurement of the concentration of oxide ions dissolved in a bath based on molten halides. The process is based on impedance measurement at a low current and a low overvoltage, between an indicator electrode, a reference electrode and a counter electrodes. The real value Z.sub.r of the impedance is determined for two frequencies, a low frequency Zr(B) (such as 15-25 Hz) and a high frequency Zr(H) (such as 10-100 kHz); the inverse of the concentration of oxide ions is a linear function of the difference between Zr(B) and Zr(H). This method has a high level of accuracy in the low ranges of concentration of oxide ions.


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