The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 29, 1989

Filed:

Sep. 16, 1987
Applicant:
Inventors:

David M Nicholas, New Tripoli, PA (US);

Jeffrey A Hopkins, Whitehall, PA (US);

Joseph P Bushinsky, Allentown, PA (US);

Assignee:

Air Products and Chemicals, Inc., Allentown, PA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01D / ;
U.S. Cl.
CPC ...
55 23 ; 55 26 ; 55 31 ; 55 58 ; 55 62 ; 55 68 ; 55 75 ;
Abstract

Substantially pure hydrogen and high purity carbon monoxide are produced and recovered from a methane-rich gas composition, such as natural gas, by subjecting such composition to steam reforming in a first stage at relatively mild conditions, followed by secondary oxidative reforming of the thus obtained primary reformate effecting conversion of residual methane therein to carbon oxides. The secondary reformate, comprised chiefly of hydrogen, CO, and CO.sub.2, is subjected to a novel sequence of operations for separation of these individual components. CO.sub.2 is first removed by solvent absorption, followed by selective adsorption for separation of CO from the CO.sub.2 -freed gas mixture with attendant recovery of hydrogen product of 98.sup.+ % purity as an unsorbed effluent. Trace to small amounts of undesired carbon monoxide in the thus recovered hydrogen product can be converted by catalytic methanation.


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