The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 25, 1989

Filed:

Sep. 04, 1987
Applicant:
Inventors:

Duane R Bujalski, Bay City, MI (US);

Gary E LeGrow, Midland, MI (US);

Jonathan Lipowitz, Midland, MI (US);

Thomas F Lim, Cuyahoga, OH (US);

Assignee:

Dow Corning Corporation, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ;
U.S. Cl.
CPC ...
525479 ; 525474 ; 528 10 ; 556430 ; 556480 ;
Abstract

Vinyl-containing polysilanes are described wherein the vinyl groups are attached to endblocking sites of intermediate reactivity. These vinyl-containing polysilanes are prepared by reacting a halogen-endblocked polysilane with, first, a non-vinyl-containing Grignard reagent or a non-vinyl organolithium compound whereby the most reactive halogen endblocking groups are replaced; then, second, reacting the resulting polysilane with vinyl Grignard reagent or vinyllithium whereby the halogen endblocking groups of intermediate reactivity are replaced; and, third, reacting the resulting polysilane with a non-vinyl-containing Grignard reagent or a non-vinyl organolithium compound whereby the least reactive halogen endblocking groups are replaced. The vinyl-containing polysilanes can be coverted to ceramic materials, including ceramic fibers, by pyrolysis.


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