The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 15, 1987

Filed:

Jul. 03, 1986
Applicant:
Inventors:

Subramaniam Mohanraj, Citrus Heights, CA (US);

Warren T Ford, Stillwater, OK (US);

Assignee:

Other;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08F / ;
U.S. Cl.
CPC ...
525351 ; 521 53 ; 521 55 ; 5253334 ; 5253591 ; 5253596 ; 525367 ;
Abstract

A method for chlorinating the pendant methyl groups of poly(p-methylstyrene) with aqueous sodium hypochlorite (e.g., laundry or swimming pool bleach) and a phase transfer catalyst (e.g., benzyltriethylammonium chloride) to provide chloromethyl-substituted polystyrenes. Conversions of up to 20 percent of methyl to chloromethyl groups were achieved with no detectable formation of dichloromethyl groups. Conversions of up to 61 percent of methyl to chloromethyl groups occur with less than 4.4 percent concomitant formation of dichloromethyl groups. The method has been applied to soluble, 1 percent cross-linked, and macroporous 20 percent cross-linked polymers.


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