The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 24, 1987

Filed:

May. 07, 1985
Applicant:
Inventors:

Marcus Baumann, Basel, CH;

Hans Bosshard, Basel, CH;

Hans Greuter, Gipf-Oberfrick, CH;

Assignee:

Ciba-Geigy Corporation, Ardsely, NY (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D / ; C07D / ;
U.S. Cl.
CPC ...
548171 ; 548170 ; 548327 ; 548329 ;
Abstract

The reaction of 2-mercapto-benzothiazole or -benzimidazole with .alpha.,.beta.-unsaturated carboxylic acid derivatives in a strongly acid reaction medium gives compounds of the formula I ##STR1## in which X is sulfur or NH, each radical R independently of one another is H, alkyl, halogenalkyl, alkoxy, alkylthio, alkylsulfonyl, phenyl, alkylphenyl, phenylalkyl, cycloalkyl, halogen, NO.sub.2, CN, COOH, COOalkyl or a tertiary amino or carbamoyl group and R.sup.1, R.sup.2 and R.sup.3 independently of one another are H, alkyl, halogenalkyl, hydroxyalkyl, alkoxyalkyl unesterified or esterified carboxyl or carboxylalkyl, carbamyol, carbamyolalkyl or unsubstituted or substituted aryl or aralkyl, or R.sup.1 and R.sup.2 together are straight-chain or branched alkylene, which can be substituted by 1 or 2 carboxyl groups, R.sup.4 is unsubstituted or substituted amino, alkoxy, cycloalkoxy, aryloxy or aralkyloxy, or R.sup.2 and R.sup.4 together are CH.sub.2 --CO--O-- or --CH.sub.2 CO--NR.sup.5 -- or R.sup.3 and R.sup.4 together are --CO--O-- or --CO--NR.sup.5 --, forming an anhydride or imide ring, wherein R.sup.5 is unsubstituted or substituted alkyl, cycloalkyl, aryl, aralkyl or hydrogen.


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