The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 06, 1986

Filed:

Sep. 25, 1984
Applicant:
Inventors:

Patrick S Nicholson, Ancaster, CA;

Kimihiro Yamashita, Hamilton, CA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C25B / ; G01N / ;
U.S. Cl.
CPC ...
204 61 ; 204421 ;
Abstract

An hydronium polycrystalline superionic conductor, having the formula (H.sub.3 O.sup.+,Na.sup.+).sub.5 (Re)Si.sub.4 O.sub.12, where Re=Y or Gd, is produced from precursor material being Na.sub.5 YSi.sub.4 O.sub.12 or Na.sub.5 GdSi.sub.4 O.sub.12. In order to accomplish the aforesaid a range of intermediate ceramics may be produced replacing part of the precursor ceramic sodium by ions of elements in 1A group of the Periodic Table that have an atomic weight above 32 and preferably ions of potassium, cesium, or mixtures of potassium and cesium. To produce the superionic hydronium polycrystalline ceramic conductor and the intermediate ceramic from the feed ceramics aforesaid, the feed ceramic is placed in a chloride melt wherein part of the sodium in the feed ceramic lattice is replaced by an appropriate cation from the melt such as potassium and cesium. Subsequently, a field assisted ionic exchange takes place to now replace the interceded potassium and cesium ions with the hydronium (H.sub.3 O.sup.+) ion, whereby the aforesaid hydronium, superionic, solid polycrystalline ceramic conductor is achieved.


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