The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Apr. 22, 1986
Filed:
Jun. 25, 1984
David J Huebner, Midland, MI (US);
John C Saam, Midland, MI (US);
Dow Corning Corporation, Midland, MI (US);
Abstract
This invention is a method of producing a latex of crosslinked polydiorganosiloxane. The latex yields an elastomer upon removal of the water. The latex is prepared by homogenizing a mixture of hydroxyl endblocked polydiorganosiloxane, less than 75 millimoles of surface active anionic catalyst per kilogram of polydiorganosiloxane where said surface active anionic catalyst is dodecylbenzene sulfonic acid or hydrogen lauryl sulfate, and water to yield an oil-in-water emulsion. This emulsion is then admixed with from 0.5 to 15 parts by weight of an alkoxy silicon compound selected from a silane of the formula R.sub.a 'Si(OR.sup.3).sub.4-a where R' is a monovalent hydrocarbon radical of up to 12 carbon atoms, R.sup.3 is an alkyl radical of 1 to 6 carbon atoms, and a is 0 or 1, a partial hydrolyzate of the silane, or mixtures of silane and partial hydrolyzate. The resulting emulsion is maintained at a temperature of about 15.degree. to 30.degree. C. for at least 5 hours at a pH of less than 5 until a crosslinked polymer is formed, then the emulsion is admixed with sufficient base to raise the pH to greater than 7. The crosslinked polymer present in the latex is reinforced by adding greater than 1 part by weight of colloidal silica sol or silsesquioxane to the latex. Removal of water from the latex results in a reinforced elastomer. This method yields a latex which can be applied and dried immediately after preparation to yield an elastomer.