The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Mar. 09, 1982
Filed:
Aug. 05, 1977
Evgeny L Styskin, Moscow, SU;
Yakov A Gurvich, Moscow, SU;
Simona T Kumok, Moscow, SU;
Olga F Starikova, Moscow, SU;
Grigory I Rutman, Sterlitamak, SU;
Jury I Michurov, Sterlitamak, SU;
Vladimir A Yanshevsky, Novokuibyshevsk Kuibyshevskoi oblasti, SU;
Vladimir K Gusev, Moscow, SU;
Alexandr G Liakumovich, Kazan, SU;
Other;
Abstract
A method for preparing sterically hindered bis- or polyphenols of the formula: ##STR1## wherein R' is hydrogen, a C.sub.1 -C.sub.4 alkyl; R' and R'' the same or different and are each: ##STR2## wherein R is a tertiary C.sub.4 -C.sub.8 alkyl, R.sub.1 and R.sub.2 are the same or different and represent a C.sub.1 -C.sub.8 alkyl or a C.sub.6 -C.sub.8 cycloalkyl, or a C.sub.7 -C.sub.9 aralkyl, which comprises reacting the starting sterically hindered 2,4,6-trialkylphenols of the formula: ##STR3## wherein A is a C.sub.1 -C.sub.8 alkyl or a C.sub.6 -C.sub.8 cycloalkyl or a C.sub.7 -C.sub.9 aralkyl or a 3,5-dialkyl-2-hydroxybenzyl of the formula: ##STR4## B is a C.sub.1 -C.sub.8 alkyl, or a C.sub.6 -C.sub.8 cycloalkyl, or a C.sub.7 -C.sub.9 aralkyl, or a 3,5-dialkyl-4-hydroxybenzyl of the formula: ##STR5## wherein R.sub.1 and R are as identified above, with acetals, aldehydes or donors of C.sub.1 -C.sub.5 aldehydes in an acidic medium at a temperature within the range of from 60.degree. to 200.degree. C. in the presence of an acidic catalyst, followed by isolation of the desired product. The method according to the present invention makes it possible to prepare sterically hindered bis- or polyphenols in a single stage, whereby the process technology is substantially simplified as compared to those of the prior art. The method of the present invention precludes formation of waste water and atmospheric pollutants. The method ensures preparation of the desired products possessing high quality in high yield without any additional crystallization.