The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 19, 1982

Filed:

Oct. 08, 1980
Applicant:
Inventors:

Kenneth G Mayhan, Irvine, CA (US);

Robert A Janssen, Irvine, CA (US);

William J Bertrand, Sunnymeade, CA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ; C08F / ; C08F / ; C08J / ;
U.S. Cl.
CPC ...
20415915 ; 20415913 ; 20415916 ; 20415917 ; 260 / ; 260 / ; 2601 / ; 525245 ; 525246 ; 525247 ; 525262 ; 525421 ; 525445 ; 525455 ; 525468 ; 525479 ; 525529 ; 525904 ;
Abstract

A process for modifying the surface characteristics of a pre-formed polymeric substrate to impart hydrophilicity, hydrophobicity, or other desired properties thereto, by peroxidizing the surface of the substrate and then allowing the active sites along the polymer chains to generate free radicals which induce graft polymerization of a suitable ethylenic monomer (or other ethylenically-unsaturated compound) onto the surface of the substrate is described. Such graft copolymerization is undertaken in the presence of variable valence metal ions in a reduced state under acidic conditions and at selected reaction times and relatively low temperatures, and in the presence of squarate ions (diketocyclobutenediol) to control the physical characteristics of the surface graft and to restore the metal ions to their lower valence state without at the same time producing deleterious by-products.


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