Process for the preparation of substantially pure cyclo aliphatic

Abstract

The instant invention is directed to a novel process for the separation of substantially pure cycloaliphatic diisocyanate reactive (cis-form) stereoisomers from cycloaliphatic diisocyanate non-reactive (trans-form) stereoisomers comprising reacting cycloaliphatic diisocyanates of the formula ##STR1## where R can be hydrogen or an aliphatic hydrocarbon group having from 1 to 4 carbon atoms, at least one of said R's being an aliphatic hydrocarbon having from 1 to 4 carbon atoms and wherein the isocyanato groups are both positioned axially or equatorially in the presence of catalysts selected from the group consisting of lead catalysts, tertiary amines, alkali metal hydroxides and sodium methoxide, thereby producing a cyclic nylon-1 type linear polymer having regularly reoccurring bicyclic structural units of the formula ##STR2## precipitating said cyclic nylon-1 type linear polymers, filtering and washing said precipitated cyclic nylon-1 type linear polymers, then decomposing said precipitated polymer using distillation, thereby producing a distillate and collecting said distillate containing a substantially pure monomer consisting of reactive (cis-form) stereoisomers. The instant invention also relates to the novel process outlined above wherein the decomposition by distillation is performed under conditions of reduced pressure.