The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 14, 1980

Filed:

May. 30, 1978
Applicant:
Inventor:

Artur Stoy, Prague, CS;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B29C / ; C08L / ;
U.S. Cl.
CPC ...
260 / ; 252316 ; 260 / ; 260 / ; 264299 ; 526221 ; 526341 ;
Abstract

Substantially water-insoluble, water-swellable crosslinked hydrogels are prepared by polymerizing monomeric material consisting predominantly of acrylonitrile in aqueous salt solution containing zinc chloride as the main component, in absence of added crosslinking agents. The concentration of acrylonitrile is in the range of about 20 to about 40% by weight, related to the weight of the polymerization batch as a whole 100%. The process is carried out by partially hydrolyzing the primary gel thus obtained which consists of polyacrylonitrile plasticized with the aqueous salt solution, whereafter the zinc ions are removed from the gel by treating it with a dilute aqueous solution of at least one electrolyte forming an insoluble precipitate therewith. The partial hydrolysis may be carried out either by increasing the acidity of the solution or temperature or both. Insoluble crosslinked hydrogels are prepared in the form of shaped articles, preferably in either closed or open molds, or in raw castings such as sheets or plates from which the final shaped articles can be manufactured by mechanical processes such as by cutting.


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