The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 23, 1979

Filed:

Jun. 22, 1978
Applicant:
Inventors:

Isaac A Angres, Gaithersburg, MD (US);

Horst G Adolph, Silver Spring, MD (US);

William Gilligan, Washington, DC (US);

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C / ;
U.S. Cl.
CPC ...
2604 / ;
Abstract

Novel bis(2-fluoro-2,2-dinitroethyl)thionocarbonate, ##STR1## is prepared from two moles of 2-fluoro-2,2-dinitroethanol and two equivats of a strong hydroxyl ion source such as sodium hydroxide or potassium hydroxide in water and one mole of thiophosgene in an organic solvent which may be methylene chloride, chloroform, or 1,2-dichloroethane. A phase transfer catalyst which may be benzyltriethylammonium chloride, tetrabutylammonium chloride, didodecyldimethylammonium bromide, or cetyltrimethylammonium chloride is used to transfer 2-fluoro-2,2-dinitroethoxy ions formed in the water phase to the organic solvent phase where they react with the thiophosgene to form the bis(2-fluoro-2,2-dinitroethyl)thionocarbonate. Bis(2-fluoro-2,2-dinitroethyl)thionocarbonate is useful as an energetic explosive.


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