The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 11, 1979

Filed:

Aug. 22, 1977
Applicant:
Inventor:

Joseph M Bollinger, North Wales, PA (US);

Assignee:

Rohm and Haas Company, Philadelphia, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F / ; C08F / ;
U.S. Cl.
CPC ...
526197 ; 2606 / ; 526328 ; 526329 ; 526344 ; 526346 ; 528-4 ;
Abstract

Polymerizable monomers are polymerized in a reaction mixture containing as catalysts (A) an oxygen source and (B) an organic boron compound which is soluble in the reaction mixture, the boron compound being (1) a diborane adduct wherein the boron atoms are linked by a hydrocarbyl group having an aliphatic carbon atom bonded to at least one of the boron atoms, or (2) oligomers based on repeating units containing at least two boron atoms linked by hydrocarbyl groups having an aliphatic carbon atom bonded to at least one of the boron atoms. The diborane adducts include the adduct of borane or a dialkylborane and 1,3-butadiene. The oligomers include polymers of diborane/propadiene adducts. The organoboron catalysts provide rapid initiation of polymerization and the polymerization is relatively insensitive to oxygen concentration, thereby permitting polymerization at ambient temperatures.


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