The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 17, 1979

Filed:

Jul. 19, 1978
Applicant:
Inventors:

John D Prater, Salt Lake City, UT (US);

Barry A Wells, Centerville, UT (US);

Assignee:

Kennecott Copper Corporation, New York, NY (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C22B / ;
U.S. Cl.
CPC ...
75117 ; 75 99 ; 75109 ; 75120 ; 75121 ; 7510 / ; 423 41 ;
Abstract

Highly toxic metallurgical waste materials from copper smelting and/or refining operations are processed on a cyclic basis for recovering copper values therefrom while protecting the environment from contamination. The waste materials, usually smelter flue dust and/or refinery sludge containing copper values and principally arsenic, bismuth, lead, antimony, and cadmium, as toxic values, with or without added sulfuric acid, are reacted in an autoclave at an overpressure atmosphere of O.sub.2. The resulting solution, pregnant with copper and still containing a significant amount of arsenic, i.e. from about 0.5 to about 2.0 grams per liter, is subjected to copper cementation on metallic iron to recover copper and to provide iron values in the solution while substantially eliminating residual toxic constituents, surprisingly without the evolution of arsine gas. The copper-barren but iron-containing solution is then recycled to the leaching step. The cement copper precipitate is smelted along with copper ore concentrates, while the solid residue from the leaching step is discharged to a tailings pond or the like as an environmentally safe, insoluble residue.


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