The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Oct. 24, 1978
Filed:
Feb. 11, 1977
Takashi Ohnishi, Kurashiki, JP;
Yoshiji Fujita, Kurashiki, JP;
Fumio Wada, Kurashiki, JP;
Takashi Nishida, Kurashiki, JP;
Yoshiaki Omura, Mitsu, JP;
Fumio Mori, Kurashiki, JP;
Takeo Hosogai, Kurashiki, JP;
Sukeji Aihara, Kurashiki, JP;
Kuraray Co., Ltd., Kurashiki, JP;
Abstract
There is disclosed a process for preparing unsaturated ketones especially terpenoid ketones, by subjecting a substituted propargyl alcohol of formula (II) ##STR1## wherein R is a group containing 1 or 2 substituted or unsubstituted alkyl- or alkylene units containing 4 carbon atoms each to a thermal treatment sufficient to rearrange its structure in order to obtain structurally isomeric unsaturated ketones of formula I ##STR2## wherein one of the substituents X.sub.3 and X.sub.4 is hydrogen and the other and Z.sub.2 together form a bond. The process can be effected in the presence of an isomerization catalyst, which leads to high percentage of .alpha...beta.,.gamma...delta.-unsaturated ketones. The ketones of formula I are useful as perfumes and as intermediates for the production of terpenoid compounds.