The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 04, 1978

Filed:

Dec. 11, 1970
Applicant:
Inventor:

Bruno J Barone, Houston, TX (US);

Assignee:

Petro-Tex Chemical Corporation, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C / ;
U.S. Cl.
CPC ...
2605 / ; 2605 / ; 2605 / ;
Abstract

Cyclic compounds, particularly cycloalkanes and cycloalkenes can be oxidized using known metal oxidation catalysts in an organic ester solvent with considerable advantage over prior art solvents. For example cyclohexane was oxidized with a combination cobalt-manganese catalyst at a conversion of 15.3 mole % to give 20.3 mole % selectivity to adipic acid. Although this is not particularly high, 70.9 mole % of the converted cyclohexane was precursors of adipic acid which on recycle to the oxidation at a conversion of 14.4 mole % (total reaction time 0.23 hours) gave 64.6 mole % selectivity to adiptic acid and a total selectivity to adipic acid and precursors of 89.2 mole %.


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