The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Jun. 20, 1978
Filed:
Sep. 14, 1976
Giuliano Fagherazzi, Novara, IT;
Francesco Ferrero, Novara, IT;
Giuseppe Sironi, Novara, IT;
Bruno Viviani, Novara, IT;
Montedison S.p.A., Milan, IT;
Abstract
A process is disclosed for preparing .alpha.-Fe.sub.2 O.sub.3 in the form of acicular particles substantially free from occluded boils or cavities, and containing from 0.2 to 2% by weight of SiO.sub.2, and having a mean axial ratio between 6 and 8, and an intrinsic coercive force of 320 - 370 Oe. An aqueous solution of FeSO.sub.4. 7H.sub.2 O is treated with alkali, in the presence of air, thus forming acicular .alpha.-FeOOH, which is then dehydrated, reduced at Fe.sub.3 O.sub.4 under fluidizing conditions, and oxidized to .gamma.-Fe.sub.2 O.sub.3 at 200.degree.-350.degree. C under fluidizing conditions. The formation of the acicular .alpha.-FeOOH is carried out at a yield of 0.5-2.5 kg of ferric Fe per hour per m.sup.3 of reactor; the reaction product is filtered and washed and the .alpha.-FeOOH particles are coated with 0.2-2% by weight of SiO.sub.2, from an aqueous suspension of .alpha.-FeOOH brought to a temperature ranging from 50.degree. to 90.degree. C, adding Na.sub.2 SiO.sub.3, and adjusting the final pH to 5.5-6.5; the .alpha.-FeOOH treated with SiO.sub.2 is dehydrated and simultaneously reduced to Fe.sub.3 O.sub.4 at a temperature between 480.degree. and 550.degree. C with a gaseous mixture selected from the class consisting of H.sub.2 + H.sub.2 O, CO + CO.sub.2, and H.sub.2 + CO + H.sub.2 O + CO.sub.2.