The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 14, 1978

Filed:

Oct. 14, 1976
Applicant:
Inventor:

Arthur G Mohan, Branchburg Township, Somerset County, NJ (US);

Assignee:

American Cyanamid Company, Stamford, CT (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D / ; C07D / ; C07D / ;
U.S. Cl.
CPC ...
542439 ; 2603 / ; 2603 / ; 542442 ; 542455 ; 542466 ; 542474 ; 542476 ; 548305 ; 548325 ;
Abstract

Process for preparing known classes of 2-substituted azoles (I) and N-acylazolinones (II) by reacting carbon monoxide at elevated temperature and pressure in the presence of a cocatalyst composition, of which 5% palladium on carbon with a Lewis acid such as ferric chloride is representative, with a nitrogenous compound (III): ##STR1## to form the products (usually in admixture): ##STR2## where R is alkyl, alkenyl, aralkyl, aryl, styrl or ##STR3## R.sub.1 and R.sub.2 are hydrogen, alkyl, alkoxy, aryl, halo or, when taken together on adjacent carbon atoms, -CH.dbd.CH-CH.dbd.CH-; R.sub.4 may be alkyl, alkenyl, aralkyl, aryl, styryl, ##STR4## X is oxygen, sulfur or imino, Y is alkylene, alkenylene or arylene; and Z is nitro, azo or azoxy.


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