The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 31, 1978

Filed:

Jul. 08, 1976
Applicant:
Inventors:

Thomas L Charlton, Rossland, CA;

Robert F Redden, Fruitvale, CA;

Horst E Hirsch, Trail, CA;

Shou C Liang, Spokane, WA (US);

Assignee:

Cominco Ltd., Vancouver, CA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C25C / ;
U.S. Cl.
CPC ...
2041 / ; 75120 ; 75121 ; 423106 ; 423127 ; 423158 ; 423119 ;
Abstract

Gallium and other values are recovered from phosphorus-furnace flue-dust by treating dust with sulfuric acid to form a solution and a residue. The residue may be treated for recovery of values. Zinc is precipitated from the solution as zinc ammonium sulfate hexahydrate and an alkaline material is added to precipitate a gallium concentrate and to form a gallium-free solution, which may be treated for recovery of sulfate and phosphate values. The gallium concentrate may be upgraded by mixing concentrate with lime to precipitate calcium phosphate and by subsequently adding sodium hydroxide to redissolve coprecipitated gallium and aluminum compounds. Residual precipitate is recycled and the solution is neutralized to precipitate an upgraded concentrate. Aluminum may be removed as calcium aluminate. Upgraded concentrate may be dissolved in alkaline solution and the solution electrolyzed for deposition and recovery of gallium.


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