The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Jan. 17, 1978
Filed:
Sep. 04, 1975
Applicant:
Inventors:
Russell E Malz, Jr, Naugatuck, CT (US);
Harold Greenfield, Watertown, CT (US);
Assignee:
Uniroyal, Inc., New York, NY (US);
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C / ;
U.S. Cl.
CPC ...
560115 ; 560-5 ;
Abstract
N-Alicyclic carbamates, useful in making polyurethanes, are prepared by nuclear hydrogenation of an N-aryl carbamate using a group VIII transition metal catalyst. E.g., dimethyl 4,4'-methylenedicarbanilate is contacted with hydrogen and ruthenium catalyst in 2-propanol medium, at 50.degree. C. for 1.3 hours under a pressure of 500-800 psi, to form dimethyl 4,4'-methylenedicyclohexylcarbamate. Acid activation of catalyst is a feature of the invention.