The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 18, 1977

Filed:

May. 11, 1976
Applicant:
Inventors:

Luciano Re, Rome, IT;

Giancarlo Eletti Bianchi, Rome, IT;

Felice Centini, Rome, IT;

Assignee:

Anic S.p.A., , IT;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C / ;
U.S. Cl.
CPC ...
2606 / ;
Abstract

In the preparation of 4-chloro-2-methyl-crotonaldehyde, an important starting material for the preparation of the acetate of Vitamin A, the improvement consisting in that isoprene monoepoxide (1:2-epoxy-2-methyl-3-butene) is chlorinated either with tert.butyl hypochlorite in the vapor phase, or with cupric chloride in the liquid phase. The reaction is preferably carried out in an inert siliceous or aluminous substrate at temperatures ranging from 60.degree. C to 150.degree. C. Lithium chloride has proven to be useful as a catalyst, but by no means essential.


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