The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 02, 1977

Filed:

Jun. 30, 1976
Applicant:
Inventors:

Carl Richard DiMartini, Piscataway, NJ (US);

William Lafayette Scott, Lebanon, NJ (US);

Assignee:

Asarco Incorporated, New York, NY (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C22B / ;
U.S. Cl.
CPC ...
75 70 ; 75 78 ; 423 94 ; 423494 ;
Abstract

Bismuth is recovered as elemental bismuth or as a Pb-Bi alloy from an air-pervious residue cake of de-bismuthizing dross of concentrated alkaline bismuthide content, by heating the cake in air to the ignition temperature of the cake to ignite the cake, and burning autogenously in a flameless or substantially flameless combustion the thus-ignited cake to oxidize the alkali and a portion of the lead to the exclusion of the bismuth. A powder-like residue, formed by the burning, comprises bismuth, lead, lead oxide and alkali oxide. The lead oxide and alkali oxide of the residue are then selectively dissolved in an oxide-dissolving flux, e.g. molten lead chloride, and the flux containing the lead oxide and alkali oxide is skimmed from the resulting lead bismuthide alloy. The lead of the alloy can, if desired, be separated to recover elemental bismuth, for example, by reacting the Pb-Bi alloy in molten droplet or molten particulate form with Cl.sub.2 to form PbCl.sub.2, by electrolysis, or by blowing the molten Pb-Bi alloy with air in a cupel to form litharge which is skimmed off.


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