The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 19, 1977

Filed:

Jun. 17, 1976
Applicant:
Inventors:

Jean-Claude Leroi, Villeurbanne, FR;

Francois Vachet, Decines, FR;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D / ; C07C / ;
U.S. Cl.
CPC ...
203 57 ; 203 58 ; 203 60 ; 203 62 ; 203 63 ; 2606 / ; 2606 / ; 203 73 ; 203 78 ;
Abstract

A method of partially or totally separating chlorinated aliphatic C.sub.1 to C.sub.3 hydrocarbons from mixtures of at least two of the chlorinated hydrocarbons by extractive distillation. The mixture of the chlorinated hydrocarbons is distilled in the presence of one or more third organic compounds having a boiling point higher than that of the substances to be separated, selected from the group comprising methyl, ethyl, normal propyl and isopropyl mono and di-chloroacetates; benzyl alcohol; salicylaldehyde, benzaldehyde, n-heptanal, methylisobutylketone, tetramethylurea, .gamma.-butyrolactone; normal propyl, isopropyl, normal, secondary and tertiary butyl acetylacetates; diethyl oxalate, dimethyl succinate and preferably methyl and ethyl acetylacetates; acetic anhydride, N-formyl-morpholine, 2-chloro ethanol, hexamethylphosphotriamide, dimethyl sulphate and normal tributyl and triisobutyl phosphates. This method is particularly applicable to separation of mixtures of 1,1,1-trichloro ethane and 1,2-dichloro ethane; trichloroethylene and 1,2-dichloro ethane; perchloroethylene and 1,1,2-trichloro ethane; and carbon tetrachloride and 1,2-dichloro ethane.


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