The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 29, 1977

Filed:

Dec. 10, 1975
Applicant:
Inventors:

Urs Karlen, Magden, CH;

Hans Morawietz, Aesch, CH;

Assignee:

Ciba-Geigy Corporation, Ardsley, NY (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C09B / ;
U.S. Cl.
CPC ...
260373 ; 260380 ; 2603455 ; 2603406 ; 2603 / ;
Abstract

A process for the manufacture of anthraquinone compounds of formula ##STR1## wherein X represents a hydrogen atom or a substituted or unsubstituted lower alkyl radical of 1 to 6 carbon atoms or a substituted or unsubstituted aryl radical, and the ring A can be further substituted, by sulphonating 1,5-dialkoxy-, 1,5-dicycloalkoxy- or diaryloxy-anthraquinone in the 2 and 6 positions, introducing two amino groups in positions 4 and 8 by treating the sulphonated intermediate with hydroxylamine or a salt thereof in sulphuric acid medium, in the presence of a metal catalyst, introducing the radical ##STR2## by reacting the boric acid complex of 1,5-dihydroxy-4,8-diaminoanthraquinone-2,6-disulphonic acid with a compound of formula ##STR3## saponifying the boric acid groups and splitting off a SO.sub.3 H group, which process comprises using 1,5-dialkoxy-, 1,5-dicycloalkoxy- or 1,5-diaryloxyanthraquinone as starting compounds and reacting them to give the end product of formula I.


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