The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 27, 1976

Filed:

May. 15, 1974
Applicant:
Inventors:

Siegfried Rosenberger, Riehen, CH;

Kurt Schwarzenbach, Pfeffingen, CH;

Assignee:

Ciba-Geigy Corporation, Ardsley, NY (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D / ;
U.S. Cl.
CPC ...
2603 / ; 260 / ; 260 / ; 260 / ; 2603 / ; 2603 / ; 2603 / ; 2604 / ; 2605709 ; 2606 / ;
Abstract

1,3,4-Oxadiazolones and 1,3,4-thiadiazolones substituted in position 3 by sterically hindered p-hydroxybenzyl and in position 5 by mono- or divalent hydrocarbon or by alkoxy or alkylthio and the 2-thiono analogs of the above defined compounds can be synthesized by hydroxybenzylation of the corresponding 3-hydrogen compounds, for instance, with formaldehyde and a sterically hindered phenol. Intermediately the 3-hydroxymethyl compounds are formed which may be isolated. The hydroxybenzylation may further be accomplished by means of the corresponding hydroxybenzyl halides, amines or dithiocarbaminates. The products are stabilizers for organic polymers to protect them against thermo-oxydative degradation. They show an outstanding stability against discoloration.


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