Method for producing high purity copper sulfate from spent acidic copper chloride etching solution

Abstract

The present disclosure relates to the fields of chemical engineering and environmental protection, and in particular to a method of preparing high purity copper sulfate by using an acidic copper chloride etching waste liquid, which includes: introducing liquid ammonia into a first acidic copper chloride etching solution and a second acidic copper chloride etching solution, mixing the obtained solutions and allowing the mixture to be subjected to crystallization and filtration to produce an intermediate copper oxychloride; washing and separating copper oxychloride and adding it into a sulfuric acid solution to obtain a copper sulfate slurry, and then adding water to the copper sulfate slurry and performing cooling, crystallization and separation to obtain Semi-finished copper sulfate; adding a first solution to Semi-finished copper sulfate and then performing heating, and temperature-controlled filtration, and performing cooling, crystallization and centrifugation on an obtained first filtrate so as to obtain a high purity copper sulfate.