Method and system for step parameter identification based on electrochemical model

Abstract

The invention discloses a method for step parameter identification based on an electrochemical model, including: identifying a first type of electrochemical parameters through a reduced-order electrochemical model by utilizing different preset charge-discharge rate data; determining a first type of target electrochemical parameters identified by the reduced-order electrochemical model through extrapolation; the first type of target electrochemical parameters including an approximate value of the first type of electrochemical parameters or the first type of electrochemical parameters at a specific rate; identifying the first type of electrochemical parameters, which includes solid-phase lithium concentration and exchange current, through a full-order electrochemical model by taking the first type of target electrochemical parameters as actual values of the first type of electrochemical parameters of the full-order electrochemical model; and identifying a second type of electrochemical parameters, which includes liquid-phase potential and liquid-phase lithium concentration, through the full-order electrochemical model.