The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 04, 2026

Filed:

Nov. 18, 2021
Applicant:

Dow Technology Investments Llc, Midland, MI (US);

Inventors:

Michael A. Brammer, Lake Jackson, TX (US);

Jason F. Giles, Missouri City, TX (US);

Glenn A. Miller, South Charleston, WV (US);

Assignee:

Dow Technology Investments LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/50 (2006.01); B01J 31/18 (2006.01);
U.S. Cl.
CPC ...
C07C 45/505 (2013.01); B01J 31/185 (2013.01);
Abstract

Embodiments of the present invention are directed to processes to improve rhodium accountability in continuous liquid recycle hydroformylation processes. In some embodiments, a process comprises contacting in a reaction zone reactants comprising C7-C20 olefins, hydrogen, and carbon monoxide in the presence of a catalyst comprising rhodium and an organomonophosphite ligand to form a reaction fluid, wherein the feed rate of olefins to the reaction zone is greater than 100 kilograms/hour; providing the reaction fluid to a strip gas vaporizer to produce a product stream and a vaporizer tails stream; measuring the C7-C20 olefin content in the vaporizer tails stream; and adding a C7-C20 olefins stream comprising at least 50 weight percent C7-C20 olefins to the vaporizer tails stream to maintain the C7-C20 content in vaporizer tails stream above 2 percent by weight.


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