The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 28, 2026

Filed:

May. 12, 2021
Applicant:

Archer Daniels Midland Company, Decatur, IL (US);

Inventors:

Andrew Ingram, Champaign, IL (US);

Erik Hagberg, Decatur, IL (US);

Chi-Cheng MA, Champaign, IL (US);

Jessica Mcclurg, Decatur, IL (US);

Kenneth Stensrud, Decatur, IL (US);

Assignee:

ARCHER DANIELS MIDLAND COMPANY, Decatur, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 51/265 (2006.01); C07C 51/25 (2006.01); C07C 61/20 (2006.01); C07C 63/26 (2006.01);
U.S. Cl.
CPC ...
C07C 51/265 (2013.01); C07C 51/25 (2013.01); C07C 61/20 (2013.01); C07C 63/26 (2013.01);
Abstract

Processes for the oxidation of carbohydrate dehydration products, such as furanics that can be oxidized to the bio-based monomer 2,5-furandicarboxylic acid (FDCA), are disclosed, according to which certain co-feeds, having been discovered to impart a beneficial reaction stabilizing effect, are oxidized together with the carbohydrate dehydration products. This can advantageously counteract, in whole or in part, detrimental effects of human impurities present in oxidation feed, with such impurities having been generated as byproducts of the upstream dehydrating step. An important co-feed is para-xylene that can be co-oxidized to form the petroleum-based monomer terephthalic acid (TPA), such that co-processing can beneficially yield two valuable monomers, while improving performance, particularly in terms of reaction stability, over comparable processes in which only the first monomer is produced. Related aspects involve opportunities for retrofitting existing monomer production facilities to enable co-processing of carbohydrate dehydration products that can lead to the above-noted advantages.


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