The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 28, 2026

Filed:

Aug. 18, 2023
Applicant:

Beijing University of Chemical Technology, Beijing, CN;

Inventors:

Yanan Liu, Beijing, CN;

Dianqing Li, Beijing, CN;

He Yu, Beijing, CN;

Ning Li, Beijing, CN;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 37/02 (2006.01); B01J 21/04 (2006.01); B01J 27/045 (2006.01); B01J 27/051 (2006.01); B01J 35/30 (2024.01); B01J 35/61 (2024.01); B01J 35/63 (2024.01); B01J 35/64 (2024.01); B01J 37/04 (2006.01); B01J 37/06 (2006.01); B01J 37/08 (2006.01); B01J 37/16 (2006.01); C07C 1/30 (2006.01); C07C 5/32 (2006.01); C07C 29/145 (2006.01);
U.S. Cl.
CPC ...
B01J 37/0201 (2013.01); B01J 21/04 (2013.01); B01J 27/045 (2013.01); B01J 27/051 (2013.01); B01J 27/0515 (2013.01); B01J 35/394 (2024.01); B01J 35/613 (2024.01); B01J 35/615 (2024.01); B01J 35/633 (2024.01); B01J 35/635 (2024.01); B01J 35/638 (2024.01); B01J 35/647 (2024.01); B01J 37/0236 (2013.01); B01J 37/04 (2013.01); B01J 37/06 (2013.01); B01J 37/08 (2013.01); B01J 37/16 (2013.01); C07C 1/30 (2013.01); C07C 5/322 (2013.01); C07C 29/145 (2013.01); C07C 2521/02 (2013.01); C07C 2523/28 (2013.01); C07C 2523/72 (2013.01); C07C 2527/051 (2013.01);
Abstract

The present invention provides a preparation method of a supported metal catalyst with synergistic sites. The method is to utilize the unsaturated cubane-like structure, M cation with catalytic activity is introduced into the cluster core unit. By using the vertex vacancy as the capturing center, and adjusting the impregnation temperature to maximize the loading of the cluster precursor, Depending on the electrostatic adsorption of the support and the confinement of the cluster structural unit, the number of S vacancies and the distance between S vacancies and Miso sites are effectively controlled through liquid phase reduction and atmosphere treatment at room temperature to obtain supported X3MSx/Al2O3 catalyst with Miso-Vs synergistic sites. The method of the present invention achieves the joint enhancement of the activity, product selectivity, and stability of unsaturated carbon oxygen bond selective hydrogenation, carbon chlorine bond selective hydrogenation dechlorination, and carbon hydrogen bond dehydrogenation reactions.


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