The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 28, 2026

Filed:

Nov. 13, 2020
Applicant:

Rensselaer Polytechnic Institute, Troy, NY (US);

Inventors:

Miao Yu, Pittsford, NY (US);

Surya Padinjarekutt, Glen Mills, PA (US);

Huazheng Li, Troy, NY (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/18 (2006.01); B01D 53/22 (2006.01); B01D 63/02 (2006.01); B01D 69/10 (2006.01); B01D 71/02 (2006.01); B01J 19/24 (2006.01); B01J 20/28 (2006.01); B01J 20/32 (2006.01); C01C 1/04 (2006.01);
U.S. Cl.
CPC ...
B01D 71/0281 (2022.08); B01D 53/228 (2013.01); B01D 53/229 (2013.01); B01D 63/02 (2013.01); B01D 69/106 (2022.08); B01J 19/2465 (2013.01); B01J 20/18 (2013.01); B01J 20/28038 (2013.01); B01J 20/3204 (2013.01); B01J 20/3238 (2013.01); B01J 20/3293 (2013.01); C01C 1/0417 (2013.01); C01C 1/0458 (2013.01); B01D 2053/224 (2013.01);
Abstract

Ammonia is made in a system that includes a conversion reactor for performing a Haber-Bosch process. Effluent streams from the conversion reactor, which include an ammonia component and excess hydrogen and nitrogen reactants, are fed to a membrane separator that includes NaA zeolite membranes disposed on one or more hollow porous supports. The NaA zeolite membranes are highly selective for the ammonia component, allowing the ammonia to be collected from a lumen of the membranes as a product and enriching the excess hydrogen and nitrogen reactants for reuse in the conversion reactor. These systems and the methods of their use are effective to replace and/or modify the energy-intensive condensation/recycling steps in the traditional Haber-Bosch process used to condense NH3 from the exiting stream of the reactor. The selective removal of ammonia by high quality NaA membranes helps to shift the ammonia evolution reaction.


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