Line edge roughness (ler) improvement of resist patterns

Abstract

Exemplary semiconductor processing methods may include a substrate housed in the processing region. A layer of silicon-containing material may be disposed on the substrate, a patterned resist material may be disposed on the layer of silicon-containing material, and a layer of carbon-containing material may be disposed on the patterned resist material and the layer of silicon-containing material. The methods may include providing a hydrogen-containing precursor, a nitrogen-containing precursor, or both to a processing region of a semiconductor processing chamber, forming plasma effluents of the hydrogen-containing precursor and/or the nitrogen-containing precursor, and contacting the substrate with the plasma effluents of the hydrogen-containing precursor and/or the nitrogen-containing precursor. The contacting may remove a portion of the layer of carbon-containing material. The methods may include providing a fluorine-containing precursor to the processing region, forming plasma effluents of the fluorine-containing precursor, and contacting the substrate with the plasma effluents of the fluorine-containing precursor.