The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 26, 2026

Filed:

Jul. 13, 2021
Applicant:

Washington State University, Pullman, WA (US);

Inventors:

Jinwen Zhang, Pullman, WA (US);

Tuan Liu, Pullman, WA (US);

Assignee:

Washington State University, Pullman, WA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 59/32 (2006.01); C08G 59/24 (2006.01); C08G 59/50 (2006.01); C09D 163/00 (2006.01);
U.S. Cl.
CPC ...
C08G 59/3218 (2013.01); C08G 59/3227 (2013.01); C08G 59/5006 (2013.01); C08G 2150/00 (2013.01);
Abstract

Disclosed is a novel room-temperature curable bio-based epoxy vitrimer with a simple design of the chemical structure. A hempseed oil-derived glycidyl ester type epoxy (HOEP) was synthesized and then blended with a bisphenol A epoxy (DER331) to manipulate the properties of the resulting vitrimer s. An aliphatic amine hardener, diethylenetriamine (DETA), was selected as hardener to realize the room temperature curing in presence of triethanolamine (TEOA) as the catalyst. Unlike the traditional glycidyl ether epoxy-amine the thermosets which are based on sable C—N and ether linkages, the epoxy vitrimer herein includes ester bonds with HOEP and hydroxyls formed from the reaction of amine and epoxy in its cross-linked network. Dynamic transesterification (DTER) between the ester bonds and hydroxyls take place at elevated temperatures, imparting the vitrimer significant stress relaxation behavior and repairability. This provided a viable method to produce room temperature curable epoxy vitrimer s.


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