Method for preparing hydrogen-rich fuel gas by catalyzing biomass tar cracking using aluminum smelting waste residues

Abstract

Disclosed is a method for preparing hydrogen-rich fuel gas, including adding aluminum smelting waste residues into medium strong acid and soaking for 2-4 h, filtering and baking obtained precipitate at 300-400° C. for 3-6 h to obtain pre-treated aluminum smelting waste residues; adding the waste residues into weak acid and performing ultrasonic treatment, performing centrifugal separation on an aluminum ash solution, baking for 3-6 h at a constant temperature of 400-500° C. in an air atmosphere, and naturally cooling to room temperature to obtain a cracking catalyst; uniformly mixing the cracking catalyst and biomass with a mass ratio of 1:1 and adding into a first-stage pyrolyzing furnace under Natmosphere, and heating from room temperature to 500-900° C. to obtain first-stage pyrolysis gas; and entering the first-stage pyrolysis gas into a second-stage pyrolyzing furnace for secondary catalytic cracking, so as to obtain hydrogen-rich fuel gas.